Sodium carbonate decahydrate



Sodium carbonate decahydrate


1. Product Identification

Synonyms: None
CAS No.: 6132-02-1 (decahydrate), 497-19-8 (anhydrous)
Molecular Weight: 286.1118
Chemical Formula: Na2CO3.10H2O
Product Codes: Analytyka: 


2. Composition/Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
6132-02-1 Sodium carbonate, decahydrate 100 unlisted
497-19-8 Sodium carbonate anhydrous - 207-838-8


Hazard Symbols:
XI
Risk Phrases:
36
 


3 - Hazards Identification
 

EMERGENCY OVERVIEW

Appearance: colorless, white semi-transparent solid. Warning! May cause severe respiratory and digestive tract irritation with possible burns. Contact with skin causes irritation and possible burns, especially if the skin is wet or moist. May cause severe eye irritation and possible injury.
Target Organs: None.


Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns.
Skin: Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation: May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic: Prolonged or repeated inhalation may cause nosebleeds, nasal congestion, erosion of the teeth, perforation of the nasal septum, chest pain and bronchitis.


4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician: Treat symptomatically and supportively.


5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:


6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.


7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.


8 - Exposure Controls, Personal Protection

Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits

Chemical Name ACGIH NIOSH OSHA - Final PELs
Sodium carbonate, decahydrate none listed none listed none listed
Sodium carbonate anhydrous none listed none listed none listed


OSHA Vacated PELs: Sodium carbonate, decahydrate: No OSHA Vacated PELs are listed for this chemical. Sodium carbonate anhydrous: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.


9 - Physical and Chemical Properties

Physical State: Solid
Appearance: colorless, white semi-transparent
Odor: none reported
pH: 11.5 @ 1% solution
Vapor Pressure: Not applicable.
Vapor Density: 9.9
Evaporation Rate:Not applicable.
Viscosity: Not applicable.
Boiling Point: Not applicable.
Freezing/Melting Point:33-34C
Decomposition Temperature:Not available.
Solubility: 21.5% @ 0C
Specific Gravity/Density:1.44
Molecular Formula:Na2CO3.10H2O
Molecular Weight:286.1118


10 - Stability and Reactivity

Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials: Reacts explosively with red hot aluminum metal. Incompatible with ammonia and silver nitrate, 2,4-dinitrotoluene, 2,4,6-trinitrotoluene, sulfuric acid, sodium sulfide and water, lithium, phosphorus pentoxide and fluorine.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, toxic fumes of sodium oxide, sodium oxide.
Hazardous Polymerization: Has not been reported


11 - Toxicological Information

RTECS#:
CAS# 6132-02-1 unlisted.
CAS# 497-19-8: VZ4050000
LD50/LC50:
Not available.

CAS# 497-19-8:
Draize test, rabbit, eye: 100 mg/24H Moderate;
Draize test, rabbit, eye: 50 mg Severe;
Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, mouse: LC50 = 1200 mg/m3/2H;
Inhalation, rat: LC50 = 2300 mg/m3/2H;
Oral, mouse: LD50 = 6600 mg/kg;
Oral, mouse: LD50 = 6600 mg/kg;
Oral, rat: LD50 = 4090 mg/kg;
Carcinogenicity:
CAS# 6132-02-1: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 497-19-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: No data available.


12 - Ecological Information

Ecotoxicity: No data available. No information found
Environmental: No information reported.
Physical: No information found
Other: No information found


13 - Disposal Considerations
 

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.


14 - Transport Information
 

  US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: No information available.       No information available.
Hazard Class:          
UN Number:          
Packing Group:          

 


15 - Regulatory Information
 

US FEDERAL

TSCA
CAS# 6132-02-1 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
CAS# 497-19-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 497-19-8: acute.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 6132-02-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 497-19-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:

R 36 Irritating to eyes.

Safety Phrases:

S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.

WGK (Water Danger/Protection)

CAS# 6132-02-1: 1
CAS# 497-19-8: 1
Canada - DSL/NDSL
CAS# 497-19-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B, E.
Canadian Ingredient Disclosure List
CAS# 497-19-8 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
 


16 - Other Information

Product Use:
Laboratory Reagent.
Revision Information:
Oct. 2003.
Disclaimer:
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ANALYTYKA provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. ANALYTYKA MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, ANALYTYKA WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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