Pentafluoropropionic anhydride
Pentafluoropropionic anhydride
1. Product Identification
Synonyms: None
CAS No.: 356-42-3
Molecular Weight: 310.04
Chemical Formula:
C6F10O3
Product Codes: A0689
2. Composition/Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 356-42-3 |
Propanoic acid, pentafluoro-, anhydride |
100 |
206-604-2 |
3. Hazards
Identification
EMERGENCY OVERVIEW
Appearance: colorless liquid.
Danger! Causes eye and skin burns. Causes digestive and
respiratory tract burns.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns.
Ingestion: May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns.
Inhalation: Causes chemical burns to the respiratory tract.
Chronic: No information found.
4. First Aid
Measures
Eyes: Get medical aid immediately. Do NOT allow victim to rub
eyes or keep eyes closed. Extensive irrigation with water is required (at least
30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with
plenty of water for at least 15 minutes while removing contaminated clothing and
shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion: Do not induce vomiting. If victim is conscious and
alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure
and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration using oxygen
and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
5. Fire Fighting
Measures
General Information: As in any fire, wear a self-contained
breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and
full protective gear. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Containers may explode
when heated.
Extinguishing Media: Use agent most appropriate to extinguish
fire. Cool containers with flooding quantities of water until well after fire is
out.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0;
Instability: 0
6. Accidental Release Measures
General Information: Use proper personal protective equipment
as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g.
vermiculite, sand or earth), then place in suitable container. Avoid runoff into
storm sewers and ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide ventilation.
7. Handling and
Storage
Handling: Wash thoroughly after handling. Remove contaminated
clothing and wash before reuse. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use with adequate
ventilation. Discard contaminated shoes.
Storage: Store in a cool, dry place. Keep container closed when
not in use. Corrosives area.
8. Exposure
Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this
material should be equipped with an eyewash facility and a safety shower. Use
adequate ventilation to keep airborne concentrations low.
Exposure Limits
|
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Propanoic acid, pentafluoro-, anhydride
|
none listed |
none listed |
none listed
|
OSHA Vacated PELs: Propanoic acid, pentafluoro-, anhydride: No
OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles and face shield.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to prevent skin
exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR
1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be
followed whenever workplace conditions warrant respirator use.
9. Physical and
Chemical Properties
Physical State: Liquid
Appearance: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 10.69
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 69 deg C
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:1.5710g/cm3
Molecular Formula:C6F10O3
Molecular Weight:310.04
10. Stability and
Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents, strong
bases, water.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
11. Toxicological
Information
RTECS#:
CAS# 356-42-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 356-42-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:
12. Ecological
Information
No information available.
13. Disposal
Considerations
Chemical waste generators must determine whether a discarded
chemical is classified as a hazardous waste. US EPA guidelines for the
classification determination are listed in 40 CFR Parts 261.3. Additionally,
waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
14. Transport
Information
| |
US DOT |
Canada TDG |
| Shipping Name: |
DOT regulated - small quantity provisions
apply (see 49CFR173.4) |
No information available. |
| Hazard Class: |
|
|
| UN Number: |
|
|
| Packing Group: |
|
|
15. Regulatory
Information
US FEDERAL
TSCA
CAS# 356-42-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances
under the CWA.
None of the chemicals in this product are listed as Priority Pollutants
under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under
the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by
OSHA.
STATE
CAS# 356-42-3 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are
listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28 After contact with skin, wash immediately with...
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
WGK (Water Danger/Protection)
CAS# 356-42-3: No information available.
Canada - DSL/NDSL
CAS# 356-42-3 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all of the information
required by those regulations.
Canadian Ingredient Disclosure List
16. Other Information
Product Use:
Laboratory Reagent.
Revision Information:
Jan. 2008.
Disclaimer:
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intended only as a guide to the appropriate precautionary handling of the
material by a properly trained person using this product. Individuals
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